Molecular Cloud Origin for Oxygen Isotopic Heterogeneity Recorded by a Primordial Spinel-rich Refractory Inclusion

1Justin I. Simon,1,2D. Kent Ross,1,3Ann N. Nguyen,4Steven B. Simon,1Scott Messenger
The Astrophysical Journal, Letters 884, L29 Link to Article [DOI
https://doi.org/10.3847/2041-8213/ab43e4]
1Astromaterials Research and Exploration Science, NASA Johnson Space Center, Houston, TX 77058, USA
2University of Texas at El Paso/Jacobs-JETS, Houston, TX 77058, USA
3Jacobs-JETS, Houston, TX 77058, USA
4Institute of Meteoritics, University of New Mexico, Albuquerque, NM 87131, USA

A spinel-rich, layered calcium- aluminum-rich spherule from the MIL 090019 CO3 chondrite contains a spinel core with a relatively 16O-rich (Δ17O ~ −18‰) and mass-fractionated oxygen isotopic composition surrounded by minerals, including spinel, that are relatively 16O-poor (Δ17O ~ −7‰), which are in turn surrounded by layers of 16O-enriched silicates (Δ17O ~ −17‰). Inclusions with refractory mineral assemblages such as this one are proposed to record inner nebula processes during the earliest epoch of solar nebula evolution. Mineralogical and textural analyses indicate that this primordial particle formed by high-temperature gas–solid reactions, partial melting, evaporation, and condensation. The radially distributed oxygen isotopic heterogeneity measured among multiple occurrences of several minerals, including spinel, requires the existence of 16O-poor gas at the beginning of solar system formation, 105 yr earlier than it can be produced by photochemical self-shielding in the solar nebula and introduced to the inner protoplanetary disk.

Formation of Interstellar C60 from Silicon Carbide Circumstellar Grains

1J. J. Bernal,2P. Haenecour,3J. Howe,2,4T. J. Zega,5S. Amari,1,6,7L. M. Ziurys
The Astrophysical Journal, Letters 883, L43 Link to Article [DOI
https://doi.org/10.3847/2041-8213/ab4206]
1Department of Chemistry and Biochemistry, University of Arizona, Tucson, AZ 85721, USA
2Lunar and Planetary Laboratory, University of Arizona, 1629 E. University Boulevard, Tucson, AZ 85721, USA
3Department of Materials Science and Engineering, and Department of Chemical Engineering and Applied Chemistry, University of Toronto, Canada
4Department of Materials Science and Engineering, University of Arizona, USA
5Physics Department and McDonnell Center for the Space Sciences, Washington University in St. Louis, 1 Brookings Drive, St. Louis, MO 63130, USA
6Department of Astronomy, Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721, USA
7Arizona Radio Observatory, Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721, USA

We have conducted laboratory experiments with analog crystalline silicon carbide (SiC) grains using transmission electron microscopy (TEM) and electron energy-loss spectroscopy (EELS). The 3C polytype of SiC was used—the type commonly produced in the envelopes of asymptotic giant branch (AGB) stars. We rapidly heated small (~50 nm) synthetic SiC crystals under vacuum to ~1300 K and bombarded them with 150 keV Xe ions. TEM imaging and EELS spectroscopic mapping show that such heating and bombardment leaches silicon from the SiC surface, creating layered graphitic sheets. Surface defects in the crystals were found to distort the six-membered rings characteristic of graphite, creating hemispherical structures with diameters matching that of C60. Such nonplanar features require the formation of five-membered rings. We also identified a circumstellar grain, preserved inside the Murchison meteorite, that contains the remnant of an SiC core almost fully encased by graphite, contradicting long-standing thermodynamic predictions of material condensation. Our combined laboratory data suggest that C60 can undergo facile formation from shock heating and ion bombardment of circumstellar SiC grains. Such heating/bombardment could occur in the protoplanetary nebula phase, accounting for the observation of C60 in these objects, in planetary nebulae (PNs) and other interstellar sources receiving PN ejecta. The synthesis of C60 in astronomical sources poses challenges, as the assembly of 60 pure carbon atoms in an H-rich environment is difficult. The formation of C60 from the surface decomposition of SiC grains is a viable mechanism that could readily occur in the heterogeneous, hydrogen-dominated gas of evolved circumstellar shells.

The Dawn of Dust Astronomy

1,2Grün, E.,3Krüger, H.,4Srama, R.
Space Science Reviews 215, 46 Link to Article [DOI: 10.1007/s11214-019-0610-1]
1Max-Planck-Institut für Kernphysik, Heidelberg, Germany
2LASP, University of Colorado, Boulder, CO, United States
3Max-Planck-Institut für Sonnensystemforschung, Göttingen, Germany
4Institut für Raumfahrtsysteme, Universität Stuttgart, Stuttgart, Germany

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Fe-ni-p-s melt pockets in elga iie iron meteorite: Evidence for the origin at high-pressures up to 20 gpa

1,2Litasov, K.D.,3Teplyakova, S.N.,1,2Shatskiy, A.,4Kuper, K.E.
Minerals 9, 616 Link to Article [DOI: 10.3390/min9100616]
1Sobolev Institute of Geology and Mineralogy SB RAS, Novosibirsk, 630090, Russian Federation
2Department of Geology and Geophysics, Novosibirsk State University, Novosibirsk, 630090, Russian Federation
3Vernadsky Institute of Geochemistry and Analytical Chemistry RAS, Moscow, 119334, Russian Federation
4Budker Institute of Nuclear Physics SB RAS, Novosibirsk, 630090, Russian Federation

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Miniaturized, rapid separation of neodymium from ultramafic and chondritic samples prior to high precision measurements of 142,143Nd/144Nd isotope ratios by TIMS

1Pin, C.,2Gannoun, A.
Journal of Analytical Atomic Spectroscopy 34, 2136-2146 Link to Article [DOI: 10.1039/c9ja00272c]
1Géologie, CNRS, Université Clermont-Auvergne, Campus des Cézeaux, 6 avenue Blaise Pascal, Aubière Cedex, 63 178, France
2Laboratoire Magmas et Volcans, Université Clermont Auvergne, CNRS, UMR 6524, OPGC-IRD, Clermont-Ferrand, F-63000, France

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Study of the Pallasite Radiation History by Track Analysis

1Alexeev, V.A.,2Bagulya, A.V.,2,3,4Volkov, A.E.,2Gippius, A.A.,2Goncharova, L.A.,2Gorbunov, S.A.,6Grachev, V.M.,3Dashkina, A.B.,1 Kalinina, G.V.,2,5Konovalova, N.S.,2,5Okateva, N.M.,1Pavlov,1T.A.,2,5,6Polukhina, N.,2,5Starkov, N.I.,2Soe, T.N.,2Chernyvsky, M.M.,2,5Shchedrina, T.V.
Bulletin of the Lebedev Physics Institute 46, 251-255 Link to Article [DOI: 10.3103/S1068335619080037]
1Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, 19 Kosygina St., Moscow, 119991, Russian Federation
2Lebedev Physical Institute, Russian Academy of Sciences, 53 Leninskii Pr., Moscow, 119991, Russian Federation
3Russian Scientific Center “Kurchatov Institute”, 1 Kurchatova Sq., Moscow, 123182, Russian Federation
4Flerov Laboratory of Nuclear Reactions, Joint Institute for Nuclear Research, 6 Joliot-Curie St., Dubna, Moscow Region, 141980, Russian Federation
5National University of Science and Technology “MISIS”, 4 Leninskii Pr., Moscow, 119049, Russian Federation
6National Research Nuclear University “MEPhI”, 31 Kashirskoe Sh., Moscow, 115409, Russian Federation

Extending the dynamic range of biomedical micro-computed tomography for application to geomaterials

1,2Edey, D.R.,1Pollmann, S.I.,1,3Lorusso, D.,1,4,5Drangova, M.,2Flemming, R.L.,1,4,5Holdsworth, D.W.
Journal of X-ray Sciences and Technology 27, 919-934 Link to Article [DOI: 10.3233/XST-190511]
1Imaging Research Laboratories, Robarts Research Institute, Schulich School of Medicine Dentistry, Western University, London, ON, Canada
2Department of Earth Sciences, Western University, London, ON, Canada
3Department of Physiology and Pharmacology, Schulich School of Medicine Dentistry, Western University, London, ON, Canada
4Department of Surgery, Schulich School of Medicine Dentistry, Western University, London, ON, Canada
5Department of Medical Biophysics, Schulich School of Medicine Dentistry, Western University, London, ON, Canada

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Measured atmospheric 36Ar/38Ar, 20Ne/22Ne, 36Ar/22Ne noble gas isotope and bulk K/U ratios constrain the early evolution of Venus and Earth

1H.Lammer,1,2M.Leitzinger,1M.Scherf,1,2P.Odert,3C.Burger,1D.Kubyshkina,3C.Johnstone,3T.Maindl,4C.M.Schäfer,3M.Güdel,5,6N.Tosi,5,6A.Nikolaou,7E.Marcq,8,9N.V.Erkaevh,10L.Noack,1K.G.Kislyakovac,1L.Fossati,3E.Pilat-Lohinger,3F.Ragossnig,3E.A.Dorfi
Icarus (in Press) Link to Artice [https://doi.org/10.1016/j.icarus.2019.113551]
1Space Research Institute, Austrian Academy of Sciences, Graz, Austria
2Institute of Physics/IGAM, University of Graz, Austria
3Department of Astrophysics, University of Vienna, Austria
4Institute of Astronomy and Astrophysics, University of Tübingen, Germany
5Institute of Planetary Research, Department of Planetary Physics, DLR, Berlin Germany
6Department of Astronomy and Astrophysics, Berlin Institute of Technology, Germany
7LATMOS, Université de Versailles Saint-Quentin-en-Yvelines, Guyancourt, France
8Institute of Computational Modelling SB RAS, Krasnoyarsk, Russian Federation
9Siberian Federal University, Krasnoyarsk, Russian Federation
10Department of Earth Sciences, Freie Universität Berlin, Germany
Copyright Elsevier

The atmospheric noble gas isotope and elemental bulk ratios on Venus and Earth provide important information on their origin and evolution. If the protoplanets grew to a certain mass (i.e. > 0.5 MEarth), they could have captured H2-dominated primordial atmospheres by accreting gas from the circumstellar disk during the formation of the Solar System, which were then quickly lost by hydrodynamic escape after the disk dissipated. In such a case, the EUV-driven hydrodynamic flow of H atoms dragged heavier elements with it at different rates, leading to changes in their initial isotope ratios. For reproducing Earth and Venus present atmospheric 36Ar/38Ar, 20Ne/22Ne, 36Ar/22Ne, isotope and bulk K/U ratios we applied hydrodynamic upper atmosphere escape and Smooth Particle Hydrodynamics (SPH) impact models for the calculation of captured H2-dominated primordial atmospheres for various protoplanetary masses. We investigated a wide range of possible EUV evolution tracks of the young Sun and initial atmospheric compositions based on mixtures of captured nebula gas, outgassed and delivered material from ureilite, enstatite and carbonaceaous chondrites. Depending on the disk lifetime of ≈ 3-5 Myr (Bollard et al., 2017; Wang et al., 2017) and the composition of accreted material after disk dispersal, we find from the reproduction of the present atmospheric Ar, Ne, and bulk K/U ratios, that early Earth’s evolution can be explained if proto-Earth had accreted masses between ≈ 0.53 − 0.58 MEarth by the time the nebula gas dissipated. If proto-Earth would have accreted a higher mass during the disk lifetime the present atmospheric Ar and Ne isotope ratios can not be reproduced with our model approach. For masses > 0.75MEarth, Earth would have had a problem to get get rid of its primordial atmosphere. If proto-Earth accreted ≈ 0.53 − 0.58MEarth of enstatite-dominated material as suggested by Dauphas (2017) during the disk lifetime, it would have captured a tiny primordial atmosphere that was lost ≈3 Myr after the disk dissipated. In such a case we find that the present-day atmospheric Ar and Ne isotope ratios can be best reproduced if the post-nebula impactors contained ≈ 5% weakly depleted carbonaceous chondritic material and ≈ 95% enstatite chondrites that are strongly depleted in Ar, Ne and moderately volatile elements like potassium. If higher amounts of carbonaceous chondrites were involved in early Earth’s accretion as recently suggested by Schiller et al. (2018), then the Earth’s present atmospheric Ar and Ne ratios can only be reproduced if the involved carbonaceous chondritic post-nebula material was also highly depleted in these noble gases and/or had to be partially be delivered as long as the primordial atmosphere was yet escaping. As long as primordial atmospheres surround the growing protoplanets the abundance of their volatile elements is overwritten by their respective captured solar-like atmospheric abundances. Therefore the initial composition of the protoplanets at the disk dispersal time can not be identified by our method. For masses less than 0.5 MEarth atmospheric escape cannot explain the present-day ratios, i.e. if Earth grew slower then these ratios have to be explained differently (Marty, 2012). If proto-Venus captured a primordial atmosphere it should have grown to masses of ≈ 0.8 − 1.0 MVenus during the time until the disk dissipated and if early Venus accreted its main mass during the disk lifetime than the present atmospheric Ar and Ne isotope ratios and the observed K/U ratios on Venus surface can also be reproduced by the escape of a captured primordial atmosphere that is lost within ≤ 100 Myr, if the Sun was born between a weakly and moderately active young G star. New precise re-measurements of atmospheric noble gases are necessary by future Venus missions to better constrain the material that was involved in the planet’s accretion history and possibly also the EUV activity evolution of the young Sun. In addition, measurements of other moderately volatile element and isotope ratios on the surface such as Rb/U, 64Zn/66Zn, and 39K/41K can give an insight on whether Venus accreted slow or fast, i.e. almost to its final mass within the disk lifetime.

Detection of Crystalline and Fine-grained Calcic Plagioclases on Vesta

1E. Palomba,1E. D’Aversa,2,3T. M. Sato,1,4A. Longobardo,1F. Dirri,5,6S. Aoki,7G. Orton,1G. Sindoni,1F. Oliva,1G. Carrozzo,8Y. Kasaba
The Astrophysical Journal, Letters 882, L22 Link to Article [DOI
https://doi.org/10.3847/2041-8213/ab339e]
1INAF-IAPS, via del Fosso del Cavaliere 100, I-00133 Rome, Italy
2ISAS-JAXA, Sagamihara, Kanagawa 252-5210, Japan
3Hokkaido Information University, Ebetsu, Hokkaido 069-8585, Japan
4DIST-Università Parthenope, Centro Direzionale Isola C4, 80143, Naples, Italy
5Planetary Aeronomy, Royal Belgian Institute for Space Aeronomy, 3 av. Circulaire, B-1180 Brussels, Belgium
6Fonds National de la Recherche Scientifique, rue d’Egmont 5, B-1000 Brussels, Belgium
7NASA/Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109, USA
8Planetary Plasma and Atmospheric Research Center, Graduate School of Science, Tohoku University, Sendai, Miyagi 980-8578, Japan

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