Quantitative in situ XRD measurement of shock metamorphism in Martian meteorites using lattice strain and strain‐related mosaicity in olivine

1,2Laura E. Jenkins, 1,2Roberta L. Flemming, 1,2Phil J. A. McCausland
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13245]
1Department of Earth Sciences, The University of Western Ontario, London, Ontario, N6A 5B7 Canada
2Centre for Planetary Science and Exploration (CPSX), The University of Western Ontario, London, Ontario, N6A 5B7 Canada
Published by arrangement with John Wiley & Sons

All Martian meteorites have experienced shock metamorphism to some degree. We quantitatively determined shock‐related strain in olivine crystals to measure shock level and peak shock pressure experienced by five Martian meteorites. Two independent methods employing nondestructive in situ micro X‐ray diffraction (μXRD) are applied, i.e., (1) the lattice strain method, in which the lattice strain value (ε) for each olivine grain is derived from a Williamson–Hall plot using its diffraction pattern (peak width variation with diffraction angle) with reference to a best fit calibration curve of ε values obtained from experimentally shocked olivine grains; (2) the strain‐related mosaicity method, allowing shock stage to be estimated by measuring the streaking along the Debye rings of olivine grain diffraction spots to define their strain‐related mosaic spread, which can then be compared with olivine mosaicity in ordinary chondrites of known shock stage. In this study, both the calculated peak shock pressures and the estimated shock stages for Dar al Gani 476 (45.6 ± 0.6 GPa), Sayh al Uhaymir 005/8 (46.1 ± 2.2 GPa), and Nakhla (18.0 ± 0.6 GPa) compare well with literature values. Formal shock assessments for North West Africa 1068/1110 (53.9 ± 2.1 GPa) and North West Africa 6234 (44.6 ± 3.1 GPa) have not been reported within the literature; however, their calculated peak shock pressures fall within the range of peak shock pressures defining their estimated shock stages. The availability of nondestructive and quantitative μXRD methods to determine shock stage and peak shock pressure from olivine crystals provides a key tool for shock metamorphism analysis.

Dynamic and isotopic evolution of ice reservoirs on Mars

1E.Vos,1,2O.Aharonson,2N.Schorghofer
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2019.01.018]
1Department of Earth and Planetary Sciences, Weizmann Institute of Science, Rehovot 76100, Israel
2Planetary Science Institute, Tucson, AZ 85719, USA
Copyright Elsevier

The layered polar caps of Mars have long been thought to be related to variations in orbit and axial tilt. We dynamically link Mars’s past climate variations with the stratigraphy and isotopic composition of its ice by modeling the exchange of H2O and HDO among three reservoirs. The model shows that the interplay among equatorial, mid-latitude, and north-polar layered deposits (NPLD) induces significant isotopic changes in the cap. The diffusive properties of the sublimation lags and dust content in our model result in a cap size consistent with current Mars. The layer thicknesses are mostly controlled by obliquity variations, but the precession period of 50 kyr dominates the variations in the isotopic composition during epochs of relatively low and nearly constant obliquity such as at present. Isotopic sampling of the top 100 m may reveal climate oscillations unseen in the layer thicknesses and would thus probe recent precession-driven climate cycles.