Rapid, molecule-free, in situ rare earth element abundances by SIMS-SSAMS

1Evan E. Groopman, 1Kenneth S. Grabowski, 2Albert J. Fahey, 3Levke Kööp
Journal of Analytical Atomic Spectrometry 32, 2153-2163 Link to Article [DOI: 10.1039/C7JA00294G]
1Materials Science and Technology Division, U.S. Naval Research Laboratory, 4555 Overlook Avenue SW, Washington, USA
2Microscopy & Surface Analysis, Corning, Inc., Corning, USA
3Department of the Geophysical Sciences, University of Chicago, 5734 S. Ellis Ave., Chicago, USA

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Cooling rates of type I chondrules from Renazzo: Implications for chondrule formation

1,2Noël Chaumard,3Munir Humayun,1Brigitte Zanda,1,4Roger H. Hewins
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.13040]
1Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie, Sorbonne Universités, Muséum national d’histoire naturelle, UPMC Université Paris 06, UMR CNRS 7590, IRD, UMR 206, Paris Cedex 05, France
2Department of Geoscience, WiscSIMS, University of Wisconsin-Madison, Madison, Wisconsin, USA
3Department of Earth, Ocean & Atmospheric Science, and National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida, USA
4Department of Earth & Planetary Sciences, Rutgers University, Piscataway, New Jersey, USA
Published by arrangement with John Wiley & Sons

Cooling rates are one of the few fundamental constraints on models of chondrule formation. In this study, we used Cu and Ga diffusion profiles in metal grains to determine the cooling rates of type I chondrules in the Renazzo CR2 chondrite. To improve previous estimations of cooling rates obtained using this method, we used CT scanning and serial polishing of our sections to analyze equatorial sections of large metal grains. Through the cores of these metal grains situated at the surface of chondrules, the cooling rates calculated range from 21 to 86 K h−1 for a peak temperature Tp ~ 1623–1673 K. A metal grain embedded in the core of a chondrule exhibits a cooling rate of 1.2 K h−1 at a Tp ~ 1573 K. We also measured Cu-Ga diffusion profiles from nonequatorial sections of metal grains and calculated a lower range of cooling rates of 15–69 K h−1 for Tp ~ 1473–1603 K compared to our results from equatorial sections. The high cooling rates inferred from the lightning model (several thousand K h−1) are clearly at odds with the values obtained in this work. The X-wind model predicts cooling rates (~6–10 K h−1) lower than most of our results. The cooling rates calculated here are in close agreement with those inferred from shock wave models, in particular for temperatures at which olivine crystallizes (from ~10 to several hundreds K h−1 between 1900 and 1500 K). However, the chemical compositions of metal grains in Renazzo are consistent with the splashing model, in which a spray of metal droplets originated from a partially molten planetesimal. Volatile siderophile element depletion is explained by evaporation before metal was engulfed within silicate droplets. Liquid metal isolated from the liquid silicate crystallized during cooling, reacted with the ambient gas, and then re-accreted within partially molten chondrules.

Shapes of chondrules determined from the petrofabric of the CR2 chondrite NWA 801

1R. J. Charles,1Pierre-Yves F. Robin,1Donald W. Davis,1,2,3Phil J. A. McCausland
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.13038]
1Department of Earth Sciences, University of Toronto, Toronto, Ontario, Canada
2Centre for Planetary Science and Exploration, Western University, London, Ontario, Canada
3Western Paleomagnetic and Petrophysical Laboratory, Western University, London, Ontario, Canada
Published by arrangement with John Wiley & Sons

The approximately spherical shapes of chondrules has long been attributed to surface tension acting on ~1 mm melt droplets that formed and cooled in the microgravity field of the solar nebula. However, chondrule shapes commonly depart significantly from spherical. In this study, 109 chondrules in a sample of CR2 chondrite NWA 801 were imaged by X-ray computed tomography and best-fitted to ellipsoids. The analysis confirms that many chondrules are indeed not spherical, and also that the chondrules’ collective shape fabric records a definite 13% compaction in the host meteorite. Dehydration of phyllosilicates within chondrules may account for that strain. However, retro-deforming all chondrules shows that a large majority were already far from spherical prior to accretion. Possible models for these initial shapes include prior deformation of individual chondrules in earlier hosts, and, as suggested by previous authors, rotation of chondrules as they were solidifying, and/or “streaming” of molten chondrules by their differential velocities with their gaseous hosts after melting. More in situ 3-D work such as this study on a variety of unequilibrated chondrites, combined with detailed structural petrography, should help further constrain these models and refine our understanding of chondrite formation.

The Varre-Sai chondrite, a Brazilian fall: petrology and geochemistry

1Caio Vinícius Gabrig Turbay Rangel, 2Marcos Tadeu D’Azeredo Orlando, 3Cláudio De Morisson Valeriano, 4Alexandre de Oliveira Chaves
International Geology Review 59, 1966-1973 Link to Article [https://doi.org/10.1080/00206814.2017.1308842]
1Geology Department, Universidade Federal do Espirito Santo, Alegre, Brasil
2Department of Physics, Universidade Federal do Espirito Santo, Alegre, Brasil
3TECTO, Universidade do Estado Rio de Janiero, Rio de Janiero, Brazil
4ICG, Universidade Federal de Minas Gerais, Belo Horizonte, Brazil

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Utilization of nondestructive techniques for analysis of the Martian meteorite NWA 6963 and its implications for astrobiology

1Bruno L. do Nascimento-Dias,1,2Davi F. de Oliveira,2Alessandra S. Machado,2Olga M.O. Araújo,2Ricardo T. Lopes,2Marcelino J. dos Anjos
X-Ray Spectrometry 47, 86-91 Link to Article [DOI: 10.1002/xrs.2815]
1Physics Institute Armando Dias Tavares, University of State of Rio de Janeiro, Rio de Janeiro, Brazil
2Nuclear Instrumentation Laboratory, PEN, COPPE, UFRJ, Rio de Janeiro, Brazil

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Crater-like structures induced by intense laser

1,2H.Zhang et al. (>10)
Applied Physics Letters 111, 184104 Link to Article [https://doi.org/10.1063/1.5010050]
1State Key Laboratory of High Field Laser Physics, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China
2University of Chinese Academy of Sciences, Beijing 100049, China

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Elemental composition analysis of stony meteorites discovered in Phitsanulok, Thailand

1,2T Loylip, 2,3S Wannawichian
Journal of Physics: Conference Series 901, 012005 Link to Article [https://doi.org/10.1088/1742-6596/901/1/012005]
1Graduate School, Chiang Mai University, Chiang Mai, Thailand
2National Astronomical Research Institute of Thailand (NARIT), Chiang Mai, Thailand
3Department of physics and Materials Science, Chiang Mai University, Chiang Mai, Thailand

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The Surface Composition of Ceres’ Ezinu quadrangle analyzed by the Dawn mission

1Jean-Philippe Combe et al. (>10)
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2017.12.039]
1Bear Fight Institute, 22 Fiddler’s Road, P.O. Box 667, Winthrop, WA 98862, USA
Copyright Elsevier

We studied the surface composition of Ceres within the limits of the Ezinu quadrangle in the ranges 180 – 270°E and 21 – 66°N by analyzing data from Dawn’s visible and near-infrared data from the Visible and InfraRed mapping spectrometer and from multispectral images from the Framing Camera. Our analysis includes the distribution of hydroxylated minerals, ammoniated phyllosilicates, carbonates, the search for organic materials and the characterization of physical properties of the regolith. The surface of this quadrangle is largely homogenous, except for small, high-albedo carbonate-rich areas, and one zone on dark, lobate materials on the floor of Occator, which constitute the main topics of investigation. 1) Carbonate-rich surface compositions are associated with H2O ice rich crust. Weaker absorption bands of hydroxylated and ammoniated minerals over the carbonate-rich areas can be explained by higher abundances of carbonates at the topmost surface. 2) Dark, smooth lobate materials at the foot of Occator’s northeastern wall possibly reveal fresh slumping of phyllosilicate-rich materials with fine grain size, or local enrichment in carbon-rich materials such as tholins. 3) The deeper absorption band depth of OH and NH4, on the rim of several impact craters, is one observation that is consistent with a stratification of the phyllosilicate abundance that has been inferred previously from global investigations.

New polarimetric and spectroscopic evidence of anomalous enrichment in spinel-bearing Calcium-Aluminium-rich Inclusions among L-type asteroids

1,2M.Devogèle et al. (>10)
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2017.12.026]
1Université de Liège, Space sciences, Technologies and Astrophysics Research (STAR) Institute, Allée du 6 Août 19c, Sart Tilman, 4000 Liège, Belgium
2Université Côte d’Azur, Observatoire de la Côte d’Azur, CNRS, Laboratoire Lagrange UMR7293, Nice, France
Copyright Elsevier

Asteroids can be classified into several groups based on their spectral reflectance. Among these groups, the one belonging to the L-class in the taxonomic classification based on visible and near-infrared spectra exhibit several peculiar properties. First, their near-infrared spectrum is characterized by a strong absorption band interpreted as the diagnostic of a high content of the FeO bearing spinel mineral. This mineral is one of the main constituents of Calcium-Aluminum-rich Inclusions (CAI) the oldest mineral compounds found in the solar system. In polarimetry, they possess an uncommonly large value of the inversion angle incompatible with all known asteroid belonging to other taxonomical classes. Asteroids found to possess such a high inversion angle are commonly called Barbarians based on the first asteroid on which this property was first identified, (234) Barbara. In this paper we present the results of an extensive campaign of polarimetric and spectroscopic observations of L-class objects. We have derived phase-polarization curves for a sample of 7 Barbarians, finding a variety of inversion angles ranging between 25 and 30°. Spectral reflectance data exhibit variations in terms of spectral slope and absorption features in the near-infrared. We analyzed these data using a Hapke model to obtain some inferences about the relative abundance of CAI and other mineral compounds. By combining spectroscopic and polarimetric results, we find evidence that the polarimetric inversion angle is directly correlated with the presence of CAI, and the peculiar polarimetric properties of Barbarians are primarily a consequence of their anomalous composition.