Noble gases in angrites Northwest Africa 1296, 2999/4931, 4590, and 4801: Evolution history inferred from noble gas signatures

1,2Daisuke Nakashima,3,4Keisuke Nagao,5Anthony J. Irving
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.13039]
1Department of Earth and Planetary Material Sciences, Faculty of Science, Tohoku University, Sendai, Miyagi, Japan
2Geochemical Research Center, Graduate School of Science, University of Tokyo, Bunkyo, Tokyo, Japan
3Geochemical Research Center, Graduate School of Science, University of Tokyo, Bunkyo, Tokyo, Japan
4Division of Polar Earth-System Sciences, Korea Polar Research Institute, Incheon, Korea
5Department of Earth & Space Sciences, University of Washington, Seattle, Washington, USA
Published by arrangement with John Wiley & Sons

Noble gases in the five angrites Northwest Africa (NWA) 1296, 2999, 4590, 4801, and 4931 were analyzed with total melting and stepwise heating methods. The noble gases consist of in situ components: spallogenic, radiogenic, nucleogenic, and fission. Cosmic-ray exposure ages of the angrites (including literature data) spread uniformly from <0.2 to 56 Ma, and coarse-grained angrites have longer exposure ages than fine-grained angrites. It is implied that the parent bodies from which the two subgroups of angrites were ejected are different and have distinct orbital elements. The 244Pu-136Xe relative ages of the angrites obtained by using 244Pu/150Nd ratios are as old as that of Angra dos Reis, reflecting their early formation. On the other hand, another method to obtain 244Pu-136Xe relative ages, using fission 136Xe, spallogenic 126Xe, and Ba/REE ratios, yields systematically older 244Pu-136Xe ages than those obtained by using 244Pu/150Nd ratios, which is explained by apparently high Ba/REE ratios caused by Ba contamination during terrestrial weathering. The 244Pu/238U ratio at 4.56 Ga of angrites is estimated as 0.0061 ± 0.0028, which is consistent with those for chondrules, chondrites, achondrites, and a terrestrial zircon. It is suggested that initial 244Pu/238U ratio has been spatially homogeneous at least in the inner part of the early solar system.

Shock history of the fossil ungrouped achondrite Österplana 065: Raman spectroscopy and TEM of relict chrome-spinel grains

1,2,3Surya S. Rout,1,2,4Philipp R. Heck,1,5Birger Schmitz
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.13041]
1Robert A. Pritzker Center for Meteoritics and Polar Studies, The Field Museum of Natural History, Chicago, Illinois, USA
2Chicago Center for Cosmochemistry, Chicago, Illinois, USA
3Physikalisches Institut, Space Research and Planetary Sciences, Universität Bern, Bern, Switzerland
4Department of the Geophysical Sciences, The University of Chicago, Chicago, Illinois, USA
5Astrogeobiology Laboratory, Department of Physics, Lund University, Lund, Sweden
Published by arrangement with John Wiley & Sons

Chrome-spinel grains from the fossil ungrouped achondrite Österplana 065 (Öst 065) recovered from Middle Ordovician limestone in Sweden were studied using Raman spectroscopy and TEM. All the studied chrome-spinel grains have a high density of planar fractures and planar features, not seen in chromites from the other L chondritic Ordovician fossil meteorites. Raman spectra of the host chrome-spinel grain and its planar features are similar and no signatures of high-pressure phases of chromite were found. The planar features occur along planar fractures, are enriched in ZnO, and are most probably produced due to enhanced leaching during terrestrial weathering in the marine sediment. Dislocation densities within two FIB sections prepared from two chrome-spinel grains from Öst 065 are similar to the dislocation densities found within chromite grains from the matrix of Tenham L6 chondrite. Using this observation and taking into account the presence of significant fracturing in all the grains, we conclude that the Öst 065 chrome-spinel grains were subjected to moderate to very strong shock corresponding to shock stages of S4–S6. This makes Öst 065 fossil achondrite the highest shocked fossil meteorite studied so far. This is consistent with the hypothesis that Öst 065 is a piece of the impactor that led to the L chondrite parent body breakup.