Formation timescales of amorphous rims on lunar grains derived from ARTEMIS observations

1,2A. R. Poppe,2,3W. M. Farrell,2,4J. S. Halekas
Journal of Geophysical Research, Planets Link to Article [DOI: 10.1002/2017JE005426]
1Space Sciences Laboratory, University of California at Berkeley, Berkeley, CA, USA
2Solar System Exploration Research Virtual Institute, NASA Ames Research Center, Moffett Field, CA, USA
3NASA Goddard Space Flight Center, Greenbelt, MD, USA
4Dept. of Physics and Astronomy, University of Iowa, Iowa City, IA, USA
Published by arrangement with John Wiley & Sons

The weathering of airless bodies exposed to space is a fundamental process in the formation and evolution of planetary surfaces. At the Moon, space weathering induces a variety of physical, chemical, and optical changes including the formation of nanometer sized amorphous rims on individual lunar grains. These rims are formed by vapor redeposition from micrometeoroid impacts and ion irradiation-induced amorphization of the crystalline matrix. For ion irradiation-induced rims, however, laboratory experiments of the depth and formation timescales of these rims stand in stark disagreement with observations of lunar soil grains. We use observations by the ARTEMIS spacecraft in orbit around the Moon to compute the mean ion flux to the lunar surface between 10 eV and 5 MeV and convolve this flux with ion irradiation-induced vacancy production rates as a function of depth calculated using the Stopping Range of Ions in Matter (SRIM) model. By combining these results with laboratory measurements of the critical fluence for charged-particle amorphization in olivine, we can predict the formation timescale of amorphous rims as a function of depth in olivinic grains. This analysis resolves two outstanding issues: (1) the provenance of >100 nm amorphous rims on lunar grains and (2) the nature of the depth-age relationship for amorphous rims on lunar grains.

A two-step K-Ar experiment on Mars: dating the diagenetic formation of jarosite from Amazonian groundwaters

1P.E.Martin et al. (>10)
Journal of Geophysical Research, Planets (in Press) Link to Article [DOI: 10.1002/2017JE005445]
1Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA, USA
Published by arrangement with John Wiley & Sons

Following K-Ar dating of a mudstone and a sandstone, a third sample has been dated by the Curiosity rover exploring Gale Crater. The Mojave 2 mudstone, which contains relatively abundant jarosite, yielded a young K-Ar bulk age of 2.57 ± 0.39 Ga (1σ precision). A two-step heating experiment was implemented in an effort to resolve the K-Ar ages of primary and secondary mineralogical components within the sample. This technique involves measurement of 40Ar released in low (500oC) and high (930oC) temperature steps, and a model of the potassium distribution within the mineralogical components of the sample. Using this method, the high-temperature step yields a K-Ar model age of 4.07 ± 0.63 Ga associated with detrital plagioclase, compatible with the age obtained on the Cumberland mudstone by Curiosity. The low-temperature step, associated with jarosite mixed with K-bearing evaporites and/or phyllosilicates, gave a youthful K-Ar model age of 2.12 ± 0.36 Ga. The interpretation of this result is complicated by the potential for argon loss after mineral formation. Comparison with the results on Cumberland and previously published constraints on argon retentivity of the individual phases likely to be present suggests that the formation age of the secondary materials, correcting for plausible extents of argon loss, is still less than 3 Ga, suggesting post-3 Ga aqueous processes occurred in the sediments in Gale Crater. Such a result is inconsistent with K-bearing mineral formation in Gale Lake, and instead suggests post-depositional fluid flow at a time after surface fluvial activity on Mars is thought to have largely ceased.