Reclassification of Hart and Northwest Africa 6047: Criteria for distinguishing between CV and CK3 chondrites

1Tasha L. Dunn, 2,3,4Juliane Gross
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.12946]
1Department of Geology, Colby College, Waterville, Maine, USA
2Department of Earth and Planetary Sciences, Rutgers University, Piscataway, New Jersey, USA
3Department of Earth and Planetary Sciences, American Museum of Natural History, New York, New York, USA
4Lunar and Planetary Institute, Houston, Texas, USA
Published by arrangement with John Wiley & Sons

The single parent body model for the CV and CK chondrites (Greenwood et al. 2010) was challenged by Dunn et al. (2016a), who argued that magnetite compositions could not be reconciled by a single metamorphic sequence (i.e., CV3 → CK3 → CK4–6). Cr isotopic compositions, which are distinguishable between the CV and CK chondrites, also support two different parent bodies (Yin et al. 2017). Despite this, there are many petrographic and mineralogical similarities between the unequilibrated (petrologic type 3) CK chondrites and the CV chondrites (also type 3), which may result in misclassification of samples. Hart and Northwest Africa 6047 (NWA 6047) are an excellent example of this. In this study, we revisit the classification of Hart and NWA 6047 using magnetite compositions, petrography, and compositions of olivine, the most ubiquitous mineral in both CV and CK chondrites. Not only do our results suggest that NWA 6047 and Hart were misclassified, but our assessment of CV and CK3 chondrites has also led to the development of criteria that can be used to distinguish between CV and CK3 chondrites. These criteria include: abundances of Cr2O3, TiO2, NiO, and Al2O3 in magnetite; Fa content and NiO abundance of matrix olivine; FeO content of chondrules; and the chondrule:matrix ratio. Classification as a CV chondrite is also supported by the presence of igneous chondrule rims, calcium-aluminum-rich inclusions, and an elongated petrofabric. However, none of these petrographic characteristics can be used conclusively to distinguish between CV and CK3 chondrites.

Carbonaceous chondrites as analogs for the composition and alteration of Ceres

H. McSween Jr. et al. (>10)
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.12947]
1Department of Earth & Planetary Sciences and Planetary Science Institute, University of Tennessee, Knoxville, Tennessee, USA
Published by arrangement with John Wiley & Sons

The mineralogy and geochemistry of Ceres, as constrained by Dawn’s instruments, are broadly consistent with a carbonaceous chondrite (CM/CI) bulk composition. Differences explainable by Ceres’s more advanced alteration include the formation of Mg-rich serpentine and ammoniated clay; a greater proportion of carbonate and lesser organic matter; amounts of magnetite, sulfide, and carbon that could act as spectral darkening agents; and partial fractionation of water ice and silicates in the interior and regolith. Ceres is not spectrally unique, but is similar to a few other C-class asteroids, which may also have suffered extensive alteration. All these bodies are among the largest carbonaceous chondrite asteroids, and they orbit in the same part of the Main Belt. Thus, the degree of alteration is apparently related to the size of the body. Although the ammonia now incorporated into clay likely condensed in the outer nebula, we cannot presently determine whether Ceres itself formed in the outer solar system and migrated inward or was assembled within the Main Belt, along with other carbonaceous chondrite bodies.

Albite dissociation reaction in the Northwest Africa 8275 shocked LL chondrite and implications for its impact history

1Masaaki Miyahara, 2Eiji Ohtani, 3,4Akira Yamaguchi
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2017.08.034]
1Department of Earth and Planetary Systems Science, Graduate School of Science, Hiroshima University, Higashi-Hiroshima, 739-8526, Japan
2Department of Earth Sciences, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
3National Institute of Polar Research, Tokyo 190-8518, Japan
4Department of Polar Science, School of Multidisciplinary Science, SOKENDAI (The Graduate University for Advanced Studies), Tokyo 190-8518, Japan
Copyright Elsevier

An impact event recorded in the Northwest Africa (NWA) 8275 LL7 ordinary chondrite was investigated based on high-pressure mineralogy of pervasive shock-melt veins present in the rock. NWA 8275 consists of olivine, low-Ca pyroxene, plagioclase (albite–oligoclase composition), and minor high-Ca pyroxene, K-feldspar, phosphate minerals, metallic Fe–Ni and iron sulfide. Plagioclase and K-feldspar grains near the shock-melt veins have transformed to amorphous, although no high-pressure polymorphs of olivine and pyroxene were identified in or adjacent the shock-melt veins. Raman spectroscopy and focused ion beam (FIB)-assisted transmission electron microscopy (TEM) observations reveal that plagioclase entrained around the center portion of the shock-melt veins has dissociated into a jadeite + coesite assemblage. Alternately stacked jadeite and coesite crystals occurred in the original plagioclase. On approaching the host rock/shock-melt vein, only jadeite is present. Based on the high-pressure polymorph assemblage, the shock pressure and temperature conditions recorded in the shock-melt veins are ∼3–12 GPa and ∼1973–2373 K, respectively. Following a Rankine–Hugoniot relationship, the impact velocity was at least ∼0.45–1.54 km/s. The duration of high-pressure and high-temperature (HPHT) conditions required for the albite dissociation reaction is estimated a maximum of ∼4–5 s using the phase transition rate of albite, implying that a body of up to ∼9–12 km across collided with the parent body of NWA 8275. The coexistence of jadeite and coesite, the latter of which rarely accompanies jadeite in shocked ordinary chondrites, as a dissociation product of albite requires relatively long duration HPHT conditions. Thus, the impact event recorded in NWA 8275 was likely caused by a larger-than-typical projectile.