Titanium isotopes and rare earth patterns in CAIs: evidence for thermal processing and gas-dust decoupling in the protoplanetary disk

1,2,3Andrew M. Davis, 1,2,4Junjun Zhang,1,2,4Nicolas D. Greber, 1,2,4Jingya Hu,1,4,5François L.H. Tissot, 1,2,3,4Nicolas Dauphas
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2017.07.032]
1Department of the Geophysical Sciences, The University of Chicago, 5734 South Ellis Avenue, Chicago, Illinois 60637, USA
2Chicago Center for Cosmochemistry, The University of Chicago, 5734 South Ellis Avenue, Chicago, Illinois 60637, USA
3Enrico Fermi Institute, The University of Chicago, 5734 South Ellis Avenue, Chicago, Illinois 60637, USA
4Origins Laboratory, The University of Chicago, 5734 South Ellis Avenue, Chicago, Illinois 60637, USA
5Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA 02139
Copyright Elsevier

Titanium isotopic compositions (mass-dependent fractionation and isotopic anomalies) were measured in 46 calcium-, aluminum-rich inclusions (CAIs) from the Allende CV chondrite. After internal normalization to 49Ti/47Ti, we found that ε50Ti values are somewhat variable among CAIs, and that ε46Ti is highly correlated with ε50Ti, with a best-fit slope of 0.162±0.030 (95% confidence interval). The linear correlation between ε46Ti and ε50Ti extends the same correlation seen among bulk solar objects (slope 0.184±0.007). This observation provides constraints on dynamic mixing of the solar disk and has implications for the nucleosynthetic origin of titanium isotopes, specifically on the possible contributions from various types of supernovae to the solar system. Titanium isotopic mass fractionation, expressed as δ′49Ti, was measured by both sample-standard bracketing and double-spiking. Most CAIs are isotopically unfractionated, within a 95% confidence interval of normal, but a few are significantly fractionated and the range δ′49Ti is from ∼–4 to ∼+4. Rare earth element patterns were measured in 37 of the CAIs. All CAIs with significant titanium mass fractionation effects have group II and related REE patterns, implying kinetically controlled volatility fractionation during the formation of CAIs with those REE patterns.

CM and CO chondrites: A common parent body or asteroidal neighbors? Insights from chondrule silicates

1,2Devin L. Schrader, 3Jemma Davidson
Geochmica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2017.07.031]
1Center for Meteorite Studies, School of Earth and Space Exploration, Arizona State University, 781 East Terrace Road, Tempe, AZ 85287-6004, USA
2Department of Mineral Sciences, National Museum of Natural History, Smithsonian Institution, 10th& Constitution Avenue NW, Washington, D.C. 20560-0119, USA
3Department of Terrestrial Magnetism, Carnegie Institution for Science, 5241 Broad Branch Road NW, Washington, DC 20015-1305, USA
Copyright Elsevier

By investigating the petrology and chemical composition of type II (FeO-rich) chondrules in the Mighei-like carbonaceous (CM) chondrites we constrain their thermal histories and relationship to the Ornans-like carbonaceous (CO) chondrites. We identified FeO-rich relict grains in type II chondrules by their Fe/Mn ratios; their presence indicates chondrule recycling among type II chondrules. The majority of relict grains in type II chondrules are FeO-poor olivine grains. Consistent with previous studies, chemical similarities between CM and CO chondrite chondrules indicate that they had similar formation conditions and that their parent bodies probably formed in a common region within the protoplanetary disk. However, important differences such as mean chondrule size and the lower abundance of FeO-poor relicts in CM chondrite type II chondrules than in CO chondrites suggest CM and CO chondrules did not form together and they likely originate from distinct parent asteroids.

Despite being aqueously altered, many CM chondrites contain pre-accretionary anhydrous minerals (i.e., olivine) that are among the least thermally metamorphosed materials in chondrites according to the Cr2O3 content of their ferroan olivine. The presence of these minimally altered pre-accretionary chondrule silicates suggests that samples to be returned from aqueously altered asteroids by the Hayabusa2 and OSIRIS-REx asteroid sample return missions, even highly hydrated, may contain silicates that can provide information about the pre-accretionary histories and conditions of asteroids Ryugu and Bennu, respectively.

Shock fabrics in fine-grained micrometeorites

1,2M. D. Suttle, 1,2M. J. Genge, 2S. S. Russell
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.12927]
1Impacts and Astromaterials Research Centre, Department of Earth Science and Engineering, Imperial College London, South Kensington, London, UK
2Department of Earth Science, The Natural History Museum, South Kensington, London, UK
Published by arrangement with John Wiley & Sons

The orientations of dehydration cracks and fracture networks in fine-grained, unmelted micrometeorites were analyzed using rose diagrams and entropy calculations. As cracks exploit pre-existing anisotropies, analysis of their orientation provides a mechanism with which to study the subtle petrofabrics preserved within fine-grained and amorphous materials. Both uniaxial and biaxial fabrics are discovered, often with a relatively wide spread in orientations (40°–60°). Brittle deformation cataclasis and rotated olivine grains are reported from a single micrometeorite. This paper provides the first evidence for impact-induced shock deformation in fine-grained micrometeorites. The presence of pervasive, low-grade shock features in CM chondrites and CM-like dust, anomalously low-density measurements for C-type asteroids, and impact experiments which suggest CM chondrites are highly prone to disruption all imply that CM parent bodies are unlikely to have remained intact and instead exist as a collection of loosely aggregated rubble-pile asteroids, composed of primitive shocked clasts.

Evidence for an impact-induced magnetic fabric in Allende, and exogenous alternatives to the core dynamo theory for Allende magnetization

1Adrian R. Muxworthy,2Phillip A. Bland,1Thomas M. Davison,1James Moore,1Gareth S. Collins,3Fred J. Ciesla
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.12918]
1Department of Earth Science and Engineering, Imperial College London, London, UK
2Department of Applied Geology, Curtin University of Technology, Perth, Western Australia, Australia
3Department of Geophysical Science, University of Chicago, Chicago, Illinois, USA
Published by arrangement with John Wiley & Sons

We conducted a paleomagnetic study of the matrix of Allende CV3 chondritic meteorite, isolating the matrix’s primary remanent magnetization, measuring its magnetic fabric and estimating the ancient magnetic field intensity. A strong planar magnetic fabric was identified; the remanent magnetization of the matrix was aligned within this plane, suggesting a mechanism relating the magnetic fabric and remanence. The intensity of the matrix’s remanent magnetization was found to be consistent and low (~6 μT). The primary magnetic mineral was found to be pyrrhotite. Given the thermal history of Allende, we conclude that the remanent magnetization was formed during or after an impact event. Recent mesoscale impact modeling, where chondrules and matrix are resolved, has shown that low-velocity collisions can generate significant matrix temperatures, as pore-space compaction attenuates shock energy and dramatically increases the amount of heating. Nonporous chondrules are unaffected, and act as heat-sinks, so matrix temperature excursions are brief. We extend this work to model Allende, and show that a 1 km/s planar impact generates bulk porosity, matrix porosity, and fabric in our target that match the observed values. Bimodal mixtures of a highly porous matrix and nominally zero-porosity chondrules make chondrites uniquely capable of recording transient or unstable fields. Targets that have uniform porosity, e.g., terrestrial impact craters, will not record transient or unstable fields. Rather than a core dynamo, it is therefore possible that the origin of the magnetic field in Allende was the impact itself, or a nebula field recorded during transient impact heating.