^1,2Craig Hardgrove,¹A. Deanne Rogers,¹Timothy, D. Glotch,^1,3Jessica, Anne Arnold
¹Stony Brook University, Department of Geosciences, Stony Brook, NY
²Arizona State University, United States
³University of Oxford, United Kingdom

Distinguishing between micro and macrocrystalline mineral phases can help constrain the conditions under which those minerals formed or the degree of post-depositional alteration. This study demonstrates the effects of crystal size and surface roughness on thermal infrared emission spectra of micro and macrocrystalline phases of the two most common minerals on Earth, quartz and calcite. Given the characteristic depositional and environmental conditions under which microcrystalline minerals form, and the recent observations of high-silica deposits on Mars, it is important to understand how these unique materials can be identified using remote infrared spectroscopy techniques. We find that (a) microcrystalline minerals exhibit naturally rough surfaces compared to their macrocrystalline counterparts at the 10 µm scale; and that (b) this roughness causes distinct spectral differences within the Reststrahlen bands of each mineral. These spectral differences occur for surfaces that are rough on the wavelength scale, where the absorption coefficient (k) is large. Specifically, the wavelength positions of the Reststrahlen features for microcrystalline phases are narrowed and shifted compared to macrocrystalline counterparts. The spectral shape differences are small enough that the composition of the material is still recognizable, but large enough such that a roughness effect could be detected. Petrographic and topographic analyses of microcrystalline samples suggest a relationship between crystal size and surface roughness. Together, these observations suggest it may be possible to make general inferences about microcrystallinity from the thermal infrared spectral character of samples, which could aid in reconstructions of sedimentary rock diagenesis where corresponding petrographic or micro-imaging is not available.

Reference
Hardgrove C, Rogers AD, Glotch TD, Arnold JA (2016) Thermal Emission Spectroscopy of Microcrystalline Sedimentary Phases: Effects of Natural Surface Roughness on Spectral Feature Shape. Journal of Geophysical Research, Planets (in Press)
Link to Article [DOI: 10.1002/2015JE004919]
Published by arrangement with John Wiley & Sons