The Vicência meteorite fall: A new unshocked (S1) weakly metamorphosed (3.2) LL chondrite

1Klaus Keil et al. (>10)*
1Hawaii Institute of Geophysics and Planetology, School of Ocean and Earth Science and Technology, University of Hawaii at Mānoa, Honolulu, Hawaii, USA
*Find the extensive, full author and affiliation list on the publishers Website

The Vicência meteorite, a stone of 1.547 kg, fell on September 21, 2013, at the village Borracha, near the city of Vicência, Pernambuco, Brazil. It was recovered immediately after the fall, and our consortium study showed it to be an unshocked (S1) LL3.2 ordinary chondrite. The LL group classification is based on the bulk density (3.13 g cm−3); the chondrule mean apparent diameter (0.9 mm); the bulk oxygen isotopic composition (δ17O = 3.768 ± 0.042‰, δ18O = 5.359 ± 0.042‰, Δ17O = 0.981 ± 0.020‰); the content of metallic Fe,Ni (1.8 vol%); the Co content of kamacite (1.73 wt%); the bulk contents of the siderophile elements Ir and Co versus Au; and the ratios of metallic Fe0/total iron (0.105) versus total Fe/Mg (1.164), and of Ni/Mg (0.057) versus total Fe/Mg. The petrologic type 3.2 classification is indicated by the beautifully developed chondritic texture, the standard deviation (~0.09) versus mean Cr2O3 content (~0.14 wt%) of ferroan olivine, the TL sensitivity and the peak temperature and peak width at half maximum, the cathodoluminescence properties of chondrules, the content of trapped 132Xetr (0.317 × 10−8cm3STP g−1), and the Raman spectra for organic material in the matrix. The cosmic ray exposure age is ~72 Ma, which is at the upper end of the age distribution of LL group chondrites. The meteorite is unusual in that it contains relatively large, up to nearly 100 μm in size, secondary fayalite grains, defined as olivine with Fa>75, large enough to allow in situ measurement of oxygen and Mn-Cr isotope systematics with SIMS. Its oxygen isotopes plot along a mass-dependent fractionation line with a slope of ~0.5 and Δ17O of 4.0 ± 0.3‰, and are similar to those of secondary fayalite and magnetite in the unequilibrated chondrites EET 90161, MET 96503, and Ngawi. These data suggest that secondary fayalite in Vicência was in equilibrium with a fluid with a Δ17O of ~4‰, consistent with the composition of the fluid in equilibrium with secondary magnetite and fayalite in other unequilibrated ordinary chondrites. Secondary fayalite and the chondrule olivine phenocrysts in Vicência are not in isotopic equilibrium, consistent with low-temperature formation of fayalite during aqueous alteration on the LL parent body. That alteration, as dated by the 53Mn-53Cr chronology age of secondary fayalite, took place inline image Ma after formation of CV CAIs when anchored to the quenched angrite D’Orbigny.

Reference
Keil K et al. (2015) The Vicência meteorite fall: A new unshocked (S1) weakly metamorphosed (3.2) LL chondrite. Meteoritics&Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.12456]
Published by arrangement with John Wiley&Sons

Geochemical studies of impact breccias and country rocks from the El’gygytgyn impact structure, Russia

1,2Ulli Raschke, 1Ralf Thomas Schmitt, 3Iain McDonald, 1,4Wolf Uwe Reimold, 5Dieter Mader, 5,6Christian Koeberl
1Museum für Naturkunde Berlin, Leibniz Institute for Evolution and Biodiversity Science, Berlin, Germany
2 Freie Universität Berlin, Institut für Geologische Wissenschaften, Berlin, Germany
3School of Earth & Ocean Sciences, Cardiff University, Cardiff, UK
4Humboldt-Universität zu Berlin, Berlin, Germany
5Department of Lithospheric Research, Center for Earth Sciences, University of Vienna, Vienna, Austria
6Natural History Museum, Vienna, Austria

The complex impact structure El’gygytgyn (age 3.6 Ma, diameter 18 km) in northeastern Russia was formed in ~88 Ma old volcanic target rocks of the Ochotsk-Chukotsky Volcanic Belt (OCVB). In 2009, El’gygytgyn was the target of a drilling project of the International Continental Scientific Drilling Program (ICDP), and in summer 2011 it was investigated further by a Russian–German expedition. Drill core material and surface samples, including volcanic target rocks and impactites, have been investigated by various geochemical techniques in order to improve the record of trace element characteristics for these lithologies and to attempt to detect and constrain a possible meteoritic component. The bedrock units of the ICDP drill core reflect the felsic volcanics that are predominant in the crater vicinity. The overlying suevites comprise a mixture of all currently known target lithologies, dominated by felsic rocks but lacking a discernable meteoritic component based on platinum group element abundances. The reworked suevite, directly overlain by lake sediments, is not only comparatively enriched in shocked minerals and impact glass spherules, but also contains the highest concentrations of Os, Ir, Ru, and Rh compared to other El’gygytgyn impactites. This is—to a lesser extent—the result of admixture of a mafic component, but more likely the signature of a chondritic meteoritic component. However, the highly siderophile element contribution from target material akin to the mafic blocks of the ICDP drill core to the impactites remains poorly constrained.

Reference
Raschke U, Schmitt RT, McDonald I, Reimold WU, Mader D, Koeberl C (2015) Geochemical studies of impact breccias and country rocks from the El’gygytgyn impact structure, Russia. Meteoritics&Planetary Science (in Press)
Link to Article [DOI: 10.1111/maps.12455]

Published by arrangement with John Wiley&Sons

Accessory and opaque minerals in impact melt rocks of the Boltysh structure, Ukraine

1E. P. Gurov, 1S. B. Shekhunova, 1V. V. Permyakov
1Institute of Geological Sciences, National Academy of Sciences of Ukraine, Kiev, Ukraine

Electron microprobe analyses of accessory and opaque minerals from the impact melt rocks of the Boltysh structure, in the central part of the Ukrainian Shield, are presented in this report. Our study establishes a variety of minerals represented by native metals, alloys, oxides, sulfides, phosphates, and silicates, formed during several stages of cooling and solidification of the thick impact melt sheet. Baddeleyite was determined to be the earliest high-temperature mineral to occur in the impact melt rocks. Iron and titanium oxides crystallized earlier or simultaneously with the microliths of orthopyroxene and feldspars. High concentrations of TiO2, Al2O3, and Cr2O3 were identified in some hematite varieties. Cu- and Ni-bearing pyrrhotites occur in impact melt rocks with a glassy matrix. Native metals—copper, platinum, and silver—were likely formed due to the hydrothermal alteration of the upper unit of the impact melt sheet. Zircon is the only accessory mineral found in impact melt rocks that is preserved from the basement granites of the Boltysh structure.

Reference
Gurov EP, Shekhunova SB, Permyakov VV (2015) Accessory and opaque minerals in impact melt rocks of the Boltysh structure, Ukraine. Meteoritics&Planetary Science (in Press)
Link to Article [DOI: 10.1111/maps.12457]

Published by arrangement with John Wiley&Sons