^1,2Devin L. Schrader, ^2,3,4,5Harold C. Connolly Jr., ²Dante S. Lauretta, ²Thomas J. Zega,
⁶Jemma Davidson,²Kenneth J. Domanik
¹Department of Mineral Sciences, National Museum of Natural History, Smithsonian Institution, Washington, District of Columbia, USA
²Lunar and Planetary Laboratory, University of Arizona, Tucson, Arizona, USA
³Department Physical Sciences, Kingsborough Community College of the City University of New York, Brooklyn, New York, USA
⁴Department of Earth and Environmental Sciences, The Graduate Center of CUNY, New York, New York, USA
⁵Department Earth and Planetary Sciences, AMNH, Central Park West, New York, New York, USA
⁶Department of Terrestrial Magnetism, Carnegie Institution of Washington, Washington, District of Columbia, USA

To better understand the formation conditions of ferromagnesian chondrules from the Renazzo-like carbonaceous (CR) chondrites, a systematic study of 210 chondrules from 15 CR chondrites was conducted. The texture and composition of silicate and opaque minerals from each observed FeO-rich (type II) chondrule, and a representative number of FeO-poor (type I) chondrules, were studied to build a substantial and self-consistent data set. The average abundances and standard deviations of Cr2O3 in FeO-rich olivine phenocrysts are consistent with previous work that the CR chondrites are among the least thermally altered samples from the early solar system. Type II chondrules from the CR chondrites formed under highly variable conditions (e.g., precursor composition, redox conditions, cooling rate), with each chondrule recording a distinct igneous history. The opaque minerals within type II chondrules are consistent with formation during chondrule melting and cooling, starting as S- and Ni-rich liquids at 988–1350 °C, then cooling to form monosulfide solid solution (mss) that crystallized around olivine/pyroxene phenocrysts. During cooling, Fe,Ni-metal crystallized from the S- and Ni-rich liquid, and upon further cooling mss decomposed into pentlandite and pyrrhotite, with pentlandite exsolving from mss at 400–600 °C. The composition, texture, and inferred formation temperature of pentlandite within chondrules studied here is inconsistent with formation via aqueous alteration. However, some opaque minerals (Fe,Ni-metal versus magnetite and panethite) present in type II chondrules are a proxy for the degree of whole-rock aqueous alteration. The texture and composition of sulfide-bearing opaque minerals in Graves Nunataks 06100 and Grosvenor Mountains 03116 suggest that they are the most thermally altered CR chondrites.

Reference
Schrader DL, Connolly Jr HC, Lauretta DS, Zega TJ, Davidson J, Domanik KJ (2014) The formation and alteration of the Renazzo-like carbonaceous chondrites III: Toward understanding the genesis of ferromagnesian chondrules. Meteoritics&Planetary Society (in Press)
Link to Article [DOI: 10.1111/maps.12402]

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