1,2,3K.T. Howard,4C.M.O’D. Alexander, 5D.L. Schrader, 6K.A. Dyl
1Kingsborough Community College of the City University of New York. 2001 Oriental Blvd. Brooklyn, NY 11235
2American Museum of Natural History
3The Natural History Museum, London
4Department of Terrestrial Magnetism, Carnegie Institution of Washington. 5241 Broad Branch Road, NW Washington, DC 20015-1305
5Smithsonian Institution, National Museum of Natural History, Washington. 10th & Constitution NW Washington, DC 20560-0119
6Department of Applied Geology, Curtin University of Technology, West Australia, Perth, WA 6845
The relative differences in the degrees of hydration should be reflected in any classification scheme for aqueously altered meteorites. Here we report the bulk mineralogies and degrees of hydration in 37 different carbonaceous chondrites: Renazzo-like (CR), Mighei-like (CM), and ungrouped (type 2) samples. This is achieved by quantifying the modal abundances of all major (phases present in abundances >1wt.%) minerals using Position Sensitive Detector X-ray Diffraction (PSD-XRD). From these modal abundances, a classification scheme is constructed that is based on the normalized fraction of phyllosilicate (View the MathML sourcetotalphyllosilicate/totalanhydroussilicate+totalphyllosilicate). Samples are linearly ranked from type 3.0 – corresponding to a phyllosilicate fraction of <0.05, to type 1.0 – corresponding to a total phyllosilicate fraction of >0.95. Powdered meteorite samples from any hydrated carbonaceous chondrite group can be ranked on this single classification scale. The resulting classifications for CRs exhibit a range from type 2.8 to 1.3, while for CMs the range is 1.7–1.2. The primary manifestation of aqueous alteration is the production of phyllosilicate, which ceased when the fluid supply was exhausted, leading to the preservation of anhydrous silicates in all samples. The variability in hydration indicates that either accretion of ices was heterogeneous or fluid was mobilized. From the bulk mineral abundances of the most hydrated samples, we infer that the initial mass fraction of H2O inside of their parent body(ies) asteroids was <20 wt.%. Bulk carbonaceous chondrite mineralogy evolved towards increasingly oxidizing assemblages as the extent of bulk hydration increased. This is consistent with the escape of reducing H2 gas that is predicted to have been produced from water during hydration reactions.
Reference
Howard KT, Alexander CMOD, Schrader DL, Dyl KA (2014) Classification of hydrous meteorites (CR, CM and C2 ungrouped) by phyllosilicate fraction: PSD-XRD modal mineralogy and planetesimal Environments. Geochimica et Cosmochimica Acta (in Press) Link to Article [DOI: 10.1016/j.gca.2014.10.025] Copyright Elsevier