Cosmochemistry Papers will be continued with a change in responsibility

Cosmochemistry Papers is appreciated and used by many people around the world. I am glad that two people indicated their interest and are willing to continue this website. I might help out from time to time, but from now on Andreas will be responsible for the site. In a few weeks we will presumably welcome the next member to the team. Thanks for this continuation and all the best!

Dominik & Andreas

Global assessment of pure crystalline plagioclase across the Moon and implications for the evolution of the primary crust

K. L. Donaldson Hanna1, L. C. Cheek1, C. M. Pieters1, J. F. Mustard1, B. T. Greenhagen2, I. R. Thomas3 and N. E. Bowles3

1Department of Geological Sciences, Brown University, Providence, Rhode Island, USA
2Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA
3Atmospheric, Oceanic, and Planetary Physics, University of Oxford, Oxford, UK

Recent advancements in visible to near infrared orbital measurements of the lunar surface have allowed the character and extent of the primary anorthositic crust to be studied at unprecedented spatial and spectral resolutions. Here we assess the lunar primary anorthositic crust in global context using a spectral parameter tool for Moon Mineralogy Mapper data to identify and map Fe-bearing crystalline plagioclase based on its diagnostic 1.25 µm absorption band. This allows plagioclase-dominated rocks, specifically anorthosites, to be unambiguously identified as well as distinguished from lithologies with minor to trace amounts of mafic minerals. Low spatial resolution global mosaics and high spatial resolution individual data strips covering more than 650 targeted craters were analyzed to identify and map the mineralogy of spectrally pure regions as small as ~400 m in size. Spectrally, pure plagioclase is identified in approximately 450 targets located across the lunar surface. Diviner thermal infrared (TIR) data are analyzed for 37 of these nearly monomineralic regions in order to understand the compositional variability of plagioclase (An#) in these areas. The average An# for each spectrally pure region is estimated using new laboratory measurements of a well-characterized anorthite (An96) sample. Diviner TIR results suggest that the plagioclase composition across the lunar highlands is relatively uniform, high in calcium content, and consistent with plagioclase compositions found in the ferroan anorthosites (An94–98). Our results confirm that spectrally pure anorthosite is widely distributed across the lunar surface, and most exposures of the ancient anorthositic crust are concentrated in regions of thicker crust surrounding impact basins on the lunar nearside and farside. In addition, the scale of the impact basins and the global nature and distribution of pure plagioclase requires a coherent zone of anorthosite of similar composition in the lunar crust supporting its formation from a single differentiation event like a magma ocean. Our identifications of pure anorthosite combined with the GRAIL crustal thickness model suggest that pure anorthosite is currently observed at a range of crustal thickness values between 9 and 63 km and that the primary anorthositic crust must have been at least 30 km thick.

Reference
Donaldson Hanna KL, Cheek LC, Pieters CM, Mustard JF, Greenhagen BT, Thomas IR, and Bowles NE (in press) Global assessment of pure crystalline plagioclase across the Moon and implications for the evolution of the primary crust. Journal of Geophysical Research: Planets
[doi:10.1002/2013JE004476]
Published by arrangement with John Wiley & Sons

Link to Article

 

Water and chlorine content in the Martian soil along the first 1900 m of the Curiosity rover traverse as estimated by the DAN instrument

I. G. Mitrofanov1 et al. (>10)*
*Find the extensive, full author and affiliation list on the publishers website.

1Department of Nuclear Planetology, Institute for Space Research of Russian Academy of Science, Moscow, Russia

The presence of hydrated phases in the soil and near-surface bedrock of Gale Crater is thought to be direct evidence for water-rock interaction in the crater in the ancient past. Layered sediments over the Gale Crater floor are thought to have formed in past epochs due to sediment transport, accumulation, and cementation through interaction with fluids, and the observed strata of water-bearing minerals record the history of these episodes. The first data analysis of the Dynamic Albedo of Neutrons (DAN) investigation on board the Curiosity rover is presented for 154 individual points of active mode measurements along 1900 m of the traverse over the first 361 Martian solar days in Gale crater. It is found that a model of constant water content within subsurface should be rejected for practically all tested points, whereas a two-layer model with different water contents in each layer is supported by the data. A so-called direct two-layer model (water content increasing with depth) yields acceptable fits for odometry ranges between 0 and 455 m and beyond 638 m. The mean water (H2O) abundances of the top and bottom layers vary from 1.5 to 1.7 wt % and from 2.2 to 3.3 wt %, respectively, while at some tested spots the water content is estimated to be as high as ~5 wt %. The data for odometry range 455–638 m support an inverse two-layer model (water content decreasing with depth), with an estimated mean water abundance of 2.1 ± 0.1 wt % and 1.4 ± 0.04 wt % in the top and bottom layers, respectively.

Reference
Mitrofanov et al. (in press) Water and chlorine content in the Martian soil along the first 1900 m of the Curiosity rover traverse as estimated by the DAN instrument. Journal of Geophysical Research: Planets
[doi:10.1002/2013JE004556]
Published by arrangement with John Wiley & Sons

Link to Article