A. A. Pavlov1, A. K. Pavlov2,3, V. M. Ostryakov3, G. I. Vasilyev2, P. Mahaffy1 and A. Steele4
1Planetary Environments Laboratory, NASA Goddard Space Flight Center, Greenbelt, Maryland, USA
2A. F. Ioffe Physico-Technical Institute of Russian Academy of Sciences, St. Petersburg, Russia
3St. Petersburg State Polytechnical University, St. Petersburg, Russia
4Geophysical Laboratory, Carnegie Institute of Washington, Washington, District of Columbia, USA
13C/12C and 15N/14N isotopic ratios are pivotal for our understanding of the Martian carbon cycle, history of the Martian atmospheric escape, and origin of the organic compounds on Mars. Here we demonstrate that the carbon and nitrogen isotopic composition of the surface rocks on Mars can be significantly altered by the continuous exposure of Martian surface to cosmic rays. Cosmic rays can effectively produce 13C and15N isotopes via spallation nuclear reactions on oxygen atoms in various Martian rocks. We calculate that in the top meter of the Martian rocks, the rates of production of both 13C and 15N due to galactic cosmic rays (GCRs) exposure can vary within 1.5–6 atoms/cm3/s depending on rocks’ depth and chemical composition. We also find that the average solar cosmic rays can produce carbon and nitrogen isotopes at a rate comparable to GCRs in the top 5–10 cm of the Martian rocks. We demonstrate that if the total carbon content in a surface Martian rock is <10 ppm, then the “light,” potentially “biological” 13C/12C ratio would be effectively erased by cosmic rays over 3.5 billion years of exposure. We found that for the rocks with relatively short exposure ages (e.g., 100 million years), cosmogenic changes in 15N/14N ratio are still very significant. We also show that a short exposure to cosmic rays of Allan Hills 84001 while on Mars can explain its high-temperature heavy nitrogen isotopic composition (15N/14N). Applications to Martian meteorites and the current Mars Science Laboratory mission are discussed.
Reference
Pavlov AA, Pavlov AK, Ostryakov VM, Vasilyev GI, Mahaffy P and Steele A (in press) Alteration of the carbon and nitrogen isotopic composition in the Martian surface rocks due to cosmic ray exposure. Journal of Geophysical Research: Planets
[doi:10.1002/2014JE004615]
Published by arrangement with John Wiley & Sons