Catherine Walsh^1,2, Tom. J. Millar², Hideko Nomura^3,4,5, Eric Herbst^6,7, Susanna Widicus Weaver⁸, Yuri Aikawa⁹, Jacob C. Laas⁸ and Anton I. Vasyunin^10,11

¹Leiden Observatory, Leiden University, PO Box 9513, 2300 RA Leiden, The Netherlands
²Astrophysics Research Centre, School of Mathematics and Physics, Queen’s University Belfast, University Road, Belfast BT7 1NN, UK
³Department of Astronomy, Graduate School of Science, Kyoto University, 606-8502 Kyoto, Japan
⁴National Astronomical Observatory of Japan, Osawa, Mitaka, Tokyo 181-8588, Japan
⁵Department of Earth and Planetary Sciences, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, 152-8551 Tokyo, Japan
⁶Departments of Physics, Chemistry and Astronomy, The Ohio State University, Columbus OH 43210, USA
⁷Departments of Chemistry, Astronomy, and Physics, University of Virginia, Charlottesville VA 22904, USA
⁸Department of Chemistry, Emory University, Atlanta GA 30322, USA
⁹Department of Earth and Planetary Sciences, Kobe University, 1-1 Rokkodai-cho, Nada, 657-8501 Kobe, Japan
¹⁰Department of Chemistry, University of Virginia, Charlottesville VA 22904, USA
¹¹Visiting Scientist, Ural Federal University, 620075 Ekaterinburg, Russia

Context. Protoplanetary disks are vital objects in star and planet formation, possessing all the material, gas and dust, which may form a planetary system orbiting the new star. Small, simple molecules have traditionally been detected in protoplanetary disks; however, in the ALMA era, we expect the molecular inventory of protoplanetary disks to significantly increase.
Aims. We investigate the synthesis of complex organic molecules (COMs) in protoplanetary disks to put constraints on the achievable chemical complexity and to predict species and transitions which may be observable with ALMA.
Methods. We have coupled a 2D steady-state physical model of a protoplanetary disk around a typical T Tauri star with a large gas-grain chemical network including COMs. We compare the resulting column densities with those derived from observations and perform ray-tracing calculations to predict line spectra. We compare the synthesised line intensities with current observations and determine those COMs which may be observable in nearby objects. We also compare the predicted grain-surface abundances with those derived from cometary comae observations.
Results. We find COMs are efficiently formed in the disk midplane via grain-surface chemical reactions, reaching peak grain-surface fractional abundances ~10^-6–10^-4 that of the H nuclei number density. COMs formed on grain surfaces are returned to the gas phase via non-thermal desorption; however, gas-phase species reach lower fractional abundances than their grain-surface equivalents, ~10^-12–10^-7. Including the irradiation of grain mantle material helps build further complexity in the ice through the replenishment of grain-surface radicals which take part in further grain-surface reactions. There is reasonable agreement with several line transitions of H₂CO observed towards T Tauri star-disk systems. There is poor agreement with HC₃N lines observed towards LkCa 15 and GO Tau and we discuss possible explanations for these discrepancies. The synthesised line intensities for CH₃OH are consistent with upper limits determined towards all sources. Our models suggest CH₃OH should be readily observable in nearby protoplanetary disks with ALMA; however, detection of more complex species may prove challenging, even with ALMA “Full Science” capabilities. Our grain-surface abundances are consistent with those derived from cometary comae observations providing additional evidence for the hypothesis that comets (and other planetesimals) formed via the coagulation of icy grains in the Sun’s natal disk.

Reference
Walsh C, Millar TJ, Nomura H, Herbst E, Weaver SW, Aikawa Y, Laas JC and Vasyunin AI (2014) Complex organic molecules in protoplanetary disks. Astronomy & Astrophysics 563:A33.
[doi:10.1051/0004-6361/201322446]
Reproduced with permission © ESO

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Sandra Pizzarello¹, Laurence A. J. Garvie²

¹Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona, USA
²Center for Meteorite Studies, Arizona State University, Tempe, Arizona, USA

Dicarboxylic acids were searched for in three Sutter’s Mill (SM) fragments (SM2 collected prerain, SM12, and SM41) and found to occur almost exclusively as linear species of 3- to 14-carbon long. Between these, concentrations were low, with measured quantities typically less than 10 nmole g⁻¹ of meteorite and a maximum of 6.8 nmole g⁻¹ of meteorite for suberic acid in SM12. The SM acids’ molecular distribution is consistent with a nonbiological origin and differs from those of CMs, such as Murchison or Murray, and of some stones of the C2-ungrouped Tagish Lake meteorite, where they are abundant and varied. Powder X-ray diffraction of SM12 and SM41 show them to be dominated by clays/amorphous material, with lesser amounts of Fe-sulfides, magnetite, and calcite. Thermal gravimetric (TG) analysis shows mass losses up to 1000 °C of 11.4% (SM12) and 9.4% (SM41). These losses are low compared with other clay-rich carbonaceous chondrites, such as Murchison (14.5%) and Orgueil (21.1%). The TG data are indicative of partially dehydrated clays, in accordance with published work on SM2, for which mineralogical studies suggest asteroidal heating to around 500 °C. In view of these compositional traits and mineralogical features, it is suggested that the dicarboxylic acids observed in the SM fragments we analyzed likely represent a combination of molecular species original to the meteorite as well as secondary products formed during parent-body alteration processes, such as asteroidal heating.

Reference
Pizzarello S and Garvie LAJ (in press) Sutter’s Mill dicarboxylic acids as possible tracers of parent-body alteration processes. Meteoritics & Planetary Science
[doi:10.1111/maps.12264]
Published by arrangement with John Wiley & Sons

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K. H. Joy¹, I. A. Crawford^2,3, G. R. Huss⁴, K. Nagashima⁴ and G. J. Taylor⁴

¹School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, UK
²Department of Earth and Planetary Sciences, Birkbeck, University of London, Bloomsbury, London, UK
³The Centre for Planetary Sciences at UCL/Birkbeck, London, UK
⁴Hawai‘i Institute of Geophysics and Planetology, School of Ocean and Earth Science and Technology, University of Hawai‘i at Mānoa, Honolulu, Hawai‘i, USA

Lunar meteorite MacAlpine Hills (MAC) 88105 is a well-studied feldspathic regolith breccia dominated by rock and mineral fragments from the lunar highlands. Thin section MAC 88105,159 contains a small rock fragment, 400 × 350 μm in size, which is compositionally anomalous compared with other MAC 88105 lithic components. The clast is composed of olivine and plagioclase with minor pyroxene and interstitial devitrified glass component. It is magnesian, akin to samples in the lunar High Mg-Suite, and also alkali-rich, akin to samples in the lunar High Alkali Suite. It could represent a small fragment of late-stage interstitial melt from an Mg-Suite parent lithology. However, olivine and pyroxene in the clast have Fe/Mn ratios and minor element concentrations that are different from known types of lunar lithologies. As Fe/Mn ratios are notably indicative of planetary origin, the clast could either (1) have a unique lunar magmatic source, or (2) have a nonlunar origin (i.e., consist of achondritic meteorite debris that survived delivery to the lunar surface). Both hypotheses are considered and discussed.

Reference
Joy KH, Crawford IA, Huss GR, Nagashima K and Taylor GJ (in press) An unusual clast in lunar meteorite MacAlpine Hills 88105: A unique lunar sample or projectile debris? Meteoritics & Planetary Science
[doi:10.1111/maps.12270]
Published by arrangement with John Wiley & Sons

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Jacob B. Simon^1,2,4 and Philip J. Armitage^2,3

¹Department of Space Studies, Southwest Research Institute, Boulder, CO 80302, USA
²JILA, University of Colorado and NIST, 440 UCB, Boulder, CO 80309-0440, USA
³Department of Astrophysical and Planetary Sciences, University of Colorado, Boulder, CO 80309, USA
⁴Sagan Fellow.

We investigate the strength of axisymmetric local pressure maxima (zonal flows) in the outer regions of protoplanetary disks, where ambipolar diffusion reduces turbulent stresses driven by the magnetorotational instability. Using local numerical simulations we show that in the absence of net vertical magnetic fields, the strength of turbulence in the ambipolar dominated region of the disk is low and any zonal flows that are present are weak. For net fields strong enough to yield observed protostellar accretion rates, however, zonal flows with a density amplitude of 10%–20% are formed. These strengths are comparable to those seen in simulations of ideal MHD disk turbulence. We investigate whether these zonal flows are able to reverse the inward radial drift of solids, leading to prolonged and enhanced concentration as a prelude to planetesimal formation. For commonly assumed mean surface density profiles (surface density Σ∝r^-1/2 or steeper) we find that the predicted perturbations to the background disk profile do not correspond to local pressure maxima. This is a consequence of radial width of the simulated zonal flows, which is larger than was assumed in prior analytic models of particle trapping. These larger scale flows would only trap particles for higher amplitude fluctuations than observed. We conclude that zonal flows are likely to be present in the outer regions of protoplanetary disks and are potentially large enough to be observable, but are unlikely to lead to strong particle trapping.

Reference
Jacob B. Simon JB and Armitage PJ (2014) Efficiency of particle trapping in the outer regions of protoplanetary disks. The Astrophysical Journal 784:15.
[doi:10.1088/0004-637X/784/1/15]

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S. Cikota¹, J. L. Ortiz², A. Cikota³, N. Morales² and G. Tancredi⁴

¹Physics Department, University of Split, Nikole Tesle 12, 21000 Split, Croatia
²Instituto de Astrofísica de Andalucía – CSIC, Apt 3004, 18008 Granada, Spain
³Institute for Astro- and Particle Physics, University of Innsbruck, Technikerstr. 25/8, 6020 Innsbruck, Austria
⁴Observatorio Astronómico Los Molinos DICYT-MEC Cno. de los Molinos 5769, 12400 Montevideo, Uruguay

It is well known that some Main Belt asteroids show comet-like features. A representative example is the first known Main Belt comet 133P/(7968) Elst-Pizarro. If the mechanisms causing this activity are too weak to develop visually evident comae or tails, the objects stay unnoticed. We are presenting a novel way to search for active asteroids, based on looking for objects with deviations from their expected brightnesses in a database. Just by using the MPCAT-OBS Observation Archive we have found five new candidate objects that possibly show a type of comet-like activity, and the already known Main Belt comet 133P/(7968) Elst-Pizarro. Four of the new candidates, (315) Constantia, (1026) Ingrid, (3646) Aduatiques, and (24 684) 1990 EU4, show brightness deviations independent of the object’s heliocentric distance, while (35 101) 1991 PL16 shows deviations dependent on its heliocentric distance, which could be an indication of a thermal triggered mechanism. The method could be implemented in future sky survey programmes to detect outbursts on Main Belt objects almost simultaneously with their occurrence.

Reference
Cikota S, Ortiz JL, Cikota A, Morales N and Tancredi G (2014) A photometric search for active Main Belt asteroids. Astronomy & Astrophysics 562:A94.
[doi:10.1051/0004-6361/201321679]
Reproduced with permission © ESO

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Alexandra I. Blinova¹, Thomas J. Zega^2,†, Christopher D. K. Herd¹ and Rhonda M. Stroud²

¹Department of Earth and Atmospheric Sciences, University of Alberta, Edmonton, Alberta, Canada
²Materials Science and Technology Division, Naval Research Laboratory, Washington, District of Columbia, USA
^†Department of of Planetary Sciences, Lunar and Planetary Laboratory, University of Arizona, Tucson, Arizona, USA

Four samples (TL5b, TL11h, TL11i, and TL11v) from the pristine collection of the Tagish Lake meteorite, an ungrouped C2 chondrite, were studied to characterize and understand its alteration history using EPMA, XRD, and TEM. We determined that samples TL11h and TL11i have a relatively smaller proportion of amorphous silicate material than sample TL5b, which experienced low-temperature hydrous parent-body alteration conditions to preserve this indigenous material. The data suggest that lithic fragments of TL11i experienced higher degrees of aqueous alteration than the rest of the matrix, based on its low porosity and high abundance of coarse- and fine-grained sheet silicates, suggesting that TL11i was present in an area of the parent body where alteration and brecciation were more extensive. We identified a coronal, “flower”-like, microstructure consisting of a fine-grained serpentine core and coarse-grained saponite-serpentine radial arrays, suggesting varied fluid chemistry and crystallization time scales. We also observed pentlandite with different morphologies: an exsolved morphology formed under nebular conditions; a nonexsolved pentlandite along grain boundaries; a “bulls-eye” sulfide morphology and rims around highly altered chondrules that probably formed by multiple precipitation episodes during low-temperature aqueous alteration (≥100 °C) on the parent body. On the basis of petrologic and mineralogic observations, we conclude that the Tagish Lake parent body initially contained a heterogeneous mixture of anhydrous precursor minerals of nebular and presolar origin. These materials were subjected to secondary, nonpervasive parent-body alteration, and the samples studied herein represent different stages of that hydrous alteration, i.e., TL5b (the least altered) < TL11h < TL11i (the most altered). Sample TL11v encompasses the petrologic characteristics of the other three specimens.

Reference
Blinova, A. I., Zega, T. J., Herd, C. D. K. and Stroud, R. M. (in press) Testing variations within the Tagish Lake meteorite—I: Mineralogy and petrology of pristine samples. Meteoritics & Planetary Science
[doi:10.1111/maps.12271]
Published by arrangement with John Wiley & Sons

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Matthias M.M. Meier^a,b and Rainer Wieler^b

^aLund University, Department of Geology, Sölvegatan 12, SE-22362 Lund, Sweden
^bETH Zürich, Department of Earth Sciences, NW-C84, Clausiusstrasse 25, CH-8092 Zürich, Switzerland

It has been argued that the decay rates of several radioactive nuclides are slightly lower at Earth’s aphelion than at perihelion, and that this effect might depend on heliocentric distance. It might then be expected that nuclear decay rates be considerably lower at larger distances from the sun, e.g., in the asteroid belt at 2–3 AU from where most meteorites originate. If so, ages of meteorites obtained by analyses of radioactive nuclides and their stable daughter isotopes might be in error, since these ages are based on decay rates determined on Earth. Here we evaluate whether the large data base on nuclear cosmochronology offers any hint for discrepancies which might be due to radially variable decay rates. Chlorine-36 (t_1/2 = 301,000 a) is produced in meteorites by interactions with cosmic rays and is the nuclide for which a decay rate dependence from heliocentric distance has been proposed, which, in principle, can be tested with our approach and the current data base. We show that compilations of ³⁶Cl concentrations measured in meteorites offer no support for a spatially variable ³⁶Cl decay rate. For very short-lived cosmic-ray produced radionuclides (half-lives < 10–100 days), the concentration should be different for meteorites hitting the Earth on the incoming vs. outgoing part of their orbit. However, the current data base of very short-lived radionuclides in freshly fallen meteorites is far from sufficient to deduce solid constraints. Constraints on the age of the Earth and the oldest meteorite phases obtained by the U–Pb dating technique give no hints for radially variable decay rates of the α-decaying nuclides ²³⁵U or ²³⁸U. Similarly, some of the oldest phases in meteorites have U–Pb ages whose differences agree almost perfectly with respective age differences obtained with “short-lived” radionuclides present in the early solar system, again indicating no variability of uranium decay rates in different meteorite parent bodies in the asteroid belt. Moreover, the oldest U–Pb ages of meteorites agree with the main-sequence age of the sun derived from helioseismology within the formal ∼1% uncertainty of the latter. Meteorite ages also provide no evidence for a decrease of decay rates with heliocentric distance for nuclides such as ⁸⁷Rb (decay mode β⁻) ⁴⁰K (β⁻ and electron capture), and ¹⁴⁷Sm (α).

Reference
Meier MMM and Wieler R (in press) No evidence for a decrease of nuclear decay rates with increasing heliocentric distance based on radiochronology of meteorites. Astroparticle Physics
[doi:10.1016/j.astropartphys.2014.01.004]
Copyright Elsevier

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Rebecca G. Martin^1,3 and Mario Livio²

¹JILA, University of Colorado & NIST, UCB 440, Boulder, CO 80309, USA
²Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218, USA
³Sagan Fellow.

CO is thought to be a vital building block for prebiotic molecules that are necessary for life. Thus, understanding where CO existed in a solid phase within the solar nebula is important for understanding the origin of life. We model the evolution of the CO snow line in a protoplanetary disk. We find that the current observed location of the CO snow line in our solar system, and in the solar system analog TW Hydra, cannot be explained by a fully turbulent disk model. With time-dependent disk models we find that the inclusion of a dead zone (a region of low turbulence) can resolve this problem. Furthermore, we obtain a fully analytic solution for the CO snow line radius for late disk evolutionary times. This will be useful for future observational attempts to characterize the demographics and predict the composition and habitability of exoplanets.

Reference
Martin RG and Livio M (2014) On the Evolution of the CO Snow Line in Protoplanetary Disks. The Astrophysical Journal – Letters 783:L28.
[doi:10.1088/2041-8205/783/2/L28]

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R. Le Gal¹, P. Hily-Blant^1,2, A. Faure¹, G. Pineau des Forêts^3,4, C. Rist¹ and S. Maret¹

¹Université Joseph Fourier/CNRS, Institut de Planétologie et d’Astrophysique de Grenoble (IPAG) UMR 5274, 38041 Grenoble, France
²Institut Universitaire de France, France 
³Université de Paris-Sud/CNRS, IAS (UMR 8617), 91405 Orsay Cedex, France
⁴LERMA/CNRS (UMR 8112)/Observatoire de Paris, 75014 Paris, France

Nitrogen, amongst the most abundant metals in the interstellar medium, has a peculiar chemistry that differs from those of carbon and oxygen. Recent observations of several nitrogen-bearing species in the interstellar medium suggest abundances in sharp disagreement with current chemical models. Although some of these observations show that some gas-grain processes are at work, gas-phase chemistry needs first to be revisited. Strong constraints are provided by recent Herschel observations of nitrogen hydrides in cold gas. The aim of the present work is to comprehensively analyse the interstellar chemistry of nitrogen, focussing on the gas-phase formation of the smallest polyatomic species and, in particular, on nitrogen hydrides. We present a new chemical network in which the kinetic rates of critical reactions have been updated based on recent experimental and theoretical studies, including nuclear spin branching ratios. Our network thus treats the different spin symmetries of the nitrogen hydrides self-consistently, together with the ortho and para forms of molecular hydrogen. This new network is used to model the time evolution of the chemical abundances in dark cloud conditions. The steady-state results are analysed, with special emphasis on the influence of the overall amounts of carbon, oxygen, and sulphur. Our calculations are also compared withHerschel/HIFI observations of NH, NH₂, and NH₃ detected towards the external envelope of the protostar IRAS 16293-2422. The observed abundances and abundance ratios are reproduced for a C/O gas-phase elemental abundance ratio of ~0.8, provided that the sulphur abundance be depleted by a factor greater than 2. The ortho-to-para ratio of H₂ in these models is ~ 10^-3. Our models also provide predictions for the ortho-to-para ratios of NH₂ and NH₃ of ~2.3 and ~0.7, respectively. We conclude that the abundances of nitrogen hydrides in dark cloud conditions are consistent with the gas-phase synthesis predicted with our new chemical network.

Reference
Le Gal R, Hily-Blant P, Faure A, des Forêts GP, Rist C and Maret S (2014) Interstellar chemistry of nitrogen hydrides in dark clouds. Astronomy & Astrophysics 562:A83.
[doi:10.1051/0004-6361/201322386]
Reproduced with permission © ESO

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