Laboratory spectroscopic detection of hydration in pristine lunar regolith

Matthew R.M. Izawaa, Edward A. Cloutisa, Daniel M. Applina, Michael A. Craigb, Paul Manna and Matthew Cuddya

aHyperspectral Optical Sensing for Extraterrestrial Reconnaissance Laboratory, Dept. Geography, University of Winnipeg, 515 Portage Avenue, Winnipeg, Manitoba R3B 2E9, Canada
bDepartment of Earth Sciences/Centre for Planetary Science and Exploration, University of Western Ontario, 1151 Richmond Street, London, Ontario N6A 5B7, Canada

Reflectance spectroscopy of Apollo lunar soil samples curated in an air- and water-free, sealed environment since recovery and return to Earth has been carried out under water-, oxygen-, CO2– and organic-controlled conditions. Spectra of these pristine samples contain features near 3 μm wavelength similar to those observed from the lunar surface by the Chandrayaan-1 Moon Mineralogy Mapper (M3), Cassini Visual and Infrared Mapping Spectrometer (VIMS), and Deep Impact Extrasolar Planet Observation and Deep Impact Extended Investigation (EPOXI) High-Resolution Instrument (HRI) instruments. Spectral feature characteristics and inferred OH/H2O concentrations are within the range of those observed by spacecraft instruments. These findings confirm that the 3 μm feature from the lunar surface results from the presence of hydration in the form of bound OH and H2O. Implantation of solar wind H+ appears to be the most plausible formation mechanism for most of the observed lunar OH and H2O.

Reference
Izawa MRM, Cloutis EA, Applin DM, Craig MA, Mann P and Cuddy M (2014) Laboratory spectroscopic detection of hydration in pristine lunar regolith. Earth and Planetary Science Letters 390:157–164.
[doi:10.1016/j.epsl.2014.01.007]
Copyright Elsevier

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