Valence determinations and oxybarometry on FIB‐sectioned olivine and pyroxene using correlated Ti, V, and Cr micro‐XAFS spectroscopy: Evaluation of ion‐milling effects and application to Antarctic micrometeorite grains

1,2S. R. Sutton,3A. J. Brearley,3,4E. DobricĂ,1A. Lanzirotti,1M. Newville,5O. Tschauner
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13603]
1Center for Advanced Radiation Sources, University of Chicago, Chicago, Illinois, 60637 USA
2Department of the Geophysical Sciences, University of Chicago, Chicago, Illinois, 60637 USA
3Department of Earth and Planetary Sciences, University of New Mexico, Albuquerque, New Mexico, 87131 USA
4Hawai’i Institute of Geophysics and Planetology, School of Ocean, Earth Science, and Technology, University of Hawai’i at Mānoa, Honolulu, Hawaii, 96822 USA
5Department of Geoscience, University of Nevada, Las Vegas, Nevada, 89154 USA
Published by arrangement with John Wiley & Sons

X‐ray absorption fine structure (XAFS) spectroscopy methods have been applied to focused ion beam (FIB) produced sections of olivine and pyroxene for determining the valence states of Ti, V, and Cr and inferring oxygen fugacities of formation for each element. High‐quality XAFS spectra were obtained for all three elements for analytical voxels of ~10 pg and usable spectra down to the pg level are achievable. The extraterrestrial samples studied here were olivine and pyroxene from chondrules in Semarkona (LL3.00), olivine from chondrules in Kainsaz (CO3.2), and an olivine and a pyroxene grain from two Antarctic micrometeorites (AMM). The general agreement between calculated thin section and FIB section valences strongly suggests that there is negligible alteration of Ti, V, and Cr valences during FIB sectioning. The inferred oxygen fugacities for the AMM olivine support an equilibrium igneous history similar to results seen for some achondrites. For the pyroxene, highly reduced Cr, coupled with relatively oxidized Ti, suggests an origin in a mildly metamorphosed chondritic parent body. These results demonstrate that this FIB and micro‐XAFS approach is promising for establishing the oxidation states of minute monomineralic grains of diverse extraterrestrial origins, including materials from sample‐return spacecraft, such as the Stardust, OSIRIS‐REx, Hayabusa, and Hayabusa2 missions.

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